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以下為定語從句中十種應該用that而不用which的情況：
一、先行詞為不定代詞,all,much,something,everything,anything,nothing,none,the one等。
例句：Have you got something (that) he wanted? 你已經得到他想要的東西了嗎?
二、先行詞被only, any, few, little, no, just, very, one of等詞修飾時。
例句：You can keep any books that you find. 你可以保留你找到的任何書。
三、先行詞是序數詞時或被序數詞修飾時。
例句：When they talked about Wuxi, the first that came into my mind is Tai Lake.當他們談到無錫時，我首先想到的是太湖。
四、先行詞是最高級或被最高級修飾時。
例句：She is the most beautiful girl in the world.她是世界上最漂亮的女孩。
五、先行詞既有人又有物,用which和who都不適合,這時宜用that。
例句：The writer and his novel that you have just talked about is really well known .你剛才談到的那個作家和他的小說真的很有名。
六、被修飾詞為數詞時。
例句：Yesterday my father caught two fish and put them in a basin of water .Now I can see the two that are still alive .昨天我父親抓了兩條魚，把它們放在一盆水里，現在我可以看到那兩條魚還活著。
七、如果有兩個從句,其中一個關系代詞已用which ,另一個關系代詞宜用that,以避免語言的單調或重復。
例句：Ben built up a factory which produced things that had never been seen before. Ben建了一家工廠，生產以前從未見過的東西。
八、疑問詞是who或which,關系代詞宜用that,以避免重復。
例句：Which is the book that you like best?你最喜歡哪本書？
九、主句是There be 結構,修飾其主句的定語從句宜用that 作關系代詞。
例句：There is still a seat in the corner that is still free.角落里還有一個空座位。
十、被修飾成分為表語時,或者關系代詞本身是定語從句的表語時,該關系代詞宜用that。
例句：That's a good book that will help you a lot.這本好書對你有很大幫助。
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